Vitamins and Minerals
Vitamins and Minerals
Vitamins and Minerals
A vitamin is an organic compound required as a nutrient in tiny amounts by an organism. A compound is called a vitamin when it cannot be synthesized in sufficient quantities by an organism, and must be obtained from the diet. Thus, the term is conditional both on the circumstances and the particular organism. For example, ascorbic acid functions as vitamin C for some animals but not others, and vitamins D and K are required in the human diet only in certain circumstances. The term vitamin does not include other essential nutrients such as dietary minerals, essential fatty acids, or essential amino acids, nor does it encompass the large number of other nutrients that promote health but are otherwise required less often.
Vitamins are classified by their biological and chemical activity, not their structure. Thus, each “vitamin” may refer to several vitamer compounds that all show the biological activity associated with a particular vitamin. Such a set of chemicals are grouped under an alphabetized vitamin “generic descriptor” title, such as “vitamin A,” which includes the compounds retinal, retinol, and many carotenoids. Vitamers are often inter-converted in the body.
Vitamins have diverse biochemical functions, including function as hormones (e.g. vitamin D), antioxidants (e.g. vitamin E), and mediators of cell signaling and regulators of cell and tissue growth and differentiation (e.g. vitamin A). The largest number of vitamins (e.g. B complex vitamins) function as precursors for enzyme cofactor bio-molecules (coenzymes), that help act as catalysts and substrates in metabolism. When acting as part of a catalyst, vitamins are bound to enzymes and are called prosthetic groups. For example, biotin is part of enzymes involved in making fatty acids. Vitamins also act as coenzymes to carry chemical groups between enzymes. For example, folic acid carries various forms of carbon group – methyl, formyl and methylene – in the cell. Although these roles in assisting enzyme reactions are vitamins’ best-known function, the other vitamin functions are equally important.
Until the 1900s, vitamins were obtained solely through food intake, and changes in diet (which, for example, could occur during a particular growing season) can alter the types and amounts of vitamins ingested. Vitamins have been produced as commodity chemicals and made widely available as inexpensive pills for several decades, allowing supplementation of the dietary intake.
A mineral is a naturally occurring solid formed through geological processes that has a characteristic chemical composition, a highly ordered atomic structure, and specific physical properties. A rock, by comparison, is an aggregate of minerals and/or mineraloids, and need not have a specific chemical composition. Minerals range in composition from pure elements and simple salts to very complex silicates with thousands of known forms.
Mineral definition and classification
To be classified as a true mineral, a substance must be a solid and have a crystalline structure. It must also be a naturally occurring, homogeneous substance with a defined chemical composition. Traditional definitions excluded organically derived material. However, the International Mineralogical Association in 1995 adopted a new definition:
a mineral is an element or chemical compound that is normally crystalline and that has been formed as a result of geological processes.
The modern classifications include an organic class – in both the new Dana and the Strunz classification schemes.
The chemical composition may vary between end members of a mineral system. For example the plagioclase feldspars comprise a continuous series from sodium and silicon-rich albite (NaAlSi3O8) to calcium and aluminium-rich anorthite (CaAl2Si2O8) with four recognized intermediate compositions between. Mineral-like substances that don’t strictly meet the definition are sometimes classified as mineraloids. Other natural-occurring substances are nonminerals. Industrial minerals is a market term and refers to commercially valuable mined materials (see also Minerals and Rocks section below).
A crystal structure is the orderly geometric spatial arrangement of atoms in the internal structure of a mineral. There are 14 basic crystal lattice arrangements of atoms in three dimensions, and these are referred to as the 14 “Bravais lattices”. Each of these lattices can be classified into one of the seven crystal systems, and all crystal structures currently recognized fit in one Bravais lattice and one crystal system. This crystal structure is based on regular internal atomic or ionic arrangement that is often expressed in the geometric form that the crystal takes. Even when the mineral grains are too small to see or are irregularly shaped, the underlying crystal structure is always periodic and can be determined by X-ray diffraction. Chemistry and crystal structure together define a mineral. In fact, two or more minerals may have the same chemical composition, but differ in crystal structure (these are known as polymorphs). For example, pyrite and marcasite are both iron sulfide, but their arrangement of atoms differs. Similarly, some minerals have different chemical compositions, but the same crystal structure: for example, halite (made from sodium and chlorine), galena (made from lead and sulfur) and periclase (made from magnesium and oxygen) all share the same cubic crystal structure.
Crystal structure greatly influences a mineral’s physical properties. For example, though diamond and graphite have the same composition (both are pure carbon), graphite is very soft, while diamond is the hardest of all known minerals. This happens because the carbon atoms in graphite are arranged into sheets which can slide easily past each other, while the carbon atoms in diamond form a strong, interlocking three-dimensional network.
There are currently more than 4,000 known minerals, according to the International Mineralogical Association, which is responsible for the approval of and naming of new mineral species found in nature. Of these, perhaps 100 can be called “common”, 50 are “occasional”, and the rest are “rare” to “extremely rare”.
